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To schedule a command on Windows NT to occur at a specific time, use "at".

at - list all pending commands
at 0:00 "c:cmd.bat" - run c:cmd.bat at midnight
at 1 /delete - delete job 1
at /delete - delete all jobs

Notes:
The cmd.bat should have an absolute pathname.
The commands in the cmd.bat should reference files with absolute pathnames.

Links:
Windows 2000 Scheduling Service
Using the Schedule Service to automate tasks
Scheduling Jobs
"AT" batch job not running as scheduled
Resource Kit for Windows NT - Winat